Volume 85, 1988
From the journal:

Faraday Discussions of the Chemical Society

Fluctuation theory of hydrogen bonding in liquids. Structure, spectral bandshapes and temperature dependence

Yuri Ya. Efimov  and  Yuri I. Naberukhin  

Abstract

The assumption of the existence in liquids of the continual distribution of configurations and energies of hydrogen bonds leading to the distribution of frequencies of OH oscillators perturbed by them allows one to construct a complete theory of stretching OH vibration bandshapes. The theory describes the temperature behaviour of the contour of uncoupled oscillators (HOD diluted in D2O) in terms of two temperature-independent functions and allows the spectra of coupled oscillators (in H2O or D2O) to be calculated. The theory is in fair agreement with experiment for water and supports the continuum model of water structure.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DC9888500117
Article type
Paper

Faraday Discuss. Chem. Soc., 1988,85, 117-123

Permissions

Request permissions

Fluctuation theory of hydrogen bonding in liquids. Structure, spectral bandshapes and temperature dependence

Y. Ya. Efimov and Y. I. Naberukhin, Faraday Discuss. Chem. Soc., 1988, 85, 117 DOI: 10.1039/DC9888500117

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements