Issue 37, 2023
From the journal:

Organic & Biomolecular Chemistry

Regioselective ortho C–H insertion of N-nitrosoanilines with naphthoquinone carbenes†

Rui-jun Peng,a   Yuan Chen,a   Xue-jing Zhang ORCID logo a  and  Ming Yan ORCID logo *a  

* Corresponding authors

a Guangdong Provincial Key Laboratory of Chiral Molecules and Drug Discovery, School of Pharmaceutical Sciences, Sun Yat-sen University, Guangzhou 510006, China
E-mail: yanming@mail.sysu.edu.cn

Abstract

A Rh(III)-catalyzed ortho C–H migratory insertion of N-nitrosoanilines with naphthoquinone carbenes has been developed. The products were obtained in good yields under mild reaction conditions. Diverse elaborations of the products were explored. This method is valuable for the synthesis of biarylamines and their derivatives.

Graphical abstract: Regioselective ortho C–H insertion of N-nitrosoanilines with naphthoquinone carbenes

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Article information

DOI
https://doi.org/10.1039/D3OB01104F
Article type
Communication
Submitted
11 Jul 2023
Accepted
30 Aug 2023
First published
31 Aug 2023

Org. Biomol. Chem., 2023,21, 7525-7529

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Regioselective ortho C–H insertion of N-nitrosoanilines with naphthoquinone carbenes

R. Peng, Y. Chen, X. Zhang and M. Yan, Org. Biomol. Chem., 2023, 21, 7525 DOI: 10.1039/D3OB01104F

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