Selective excision of the MoII vertex in the mixed-valent, adamantanoid cage complex Mo(CO)4[Pri2NPO]4Mo(CO)2I2 with sodium dithiocarbamate gave the metalla-ligand Mo(CO)4[Pri2NPO]4 which is a precursor to novel heterobimetallic cage complexes Mo(CO)4[Pri2NPO]4MLn where MLn can be Cr(CO)4, W(CO)4, Fe(CO)3, NiBr2, PtCl2 or Cu(MeCN)2BF4.
H. Yang, E. H. Wong, A. L. Rheingold and B. E. Owens-Waltermire, J. Chem. Soc., Chem. Commun., 1993, 35 DOI: 10.1039/C39930000035
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