Electron energy loss and thermal desorption spectroscopies have been used to show that at 300–350 K toluene adsorbed on a Pt(111) surface is selectively dehydrogenated to give an adsorbed η7-benzyl which is π-bonded through the arene and σ-bonded through the methylene side group.
N. R. Avery, J. Chem. Soc., Chem. Commun., 1988, 153 DOI: 10.1039/C39880000153
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