Issue 7, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Nucleophilic addition at the bridging ethynyl ligand in [Os3H(µ-3-C[triple bond, length half m-dash]CH)(CO)9] and hydrolytic cleavage of the carbon–carbon triple bond

Esther Boyar,   Antony J. Deeming  and  Shariff E. Kabir  

Abstract

The addition of ethanol, ammonia, diethylamine, pyridine etc. at [Os3H(µ3-C[triple bond, length half m-dash]CH)(CO)9] gives clusters containing the new triply bridging ligands EtOCCH, CCHOEt, NH2CCH, Et2NCCH etc., while the reaction of water with [Os3H2(µ3-C[triple bond, length half m-dash]CH)(CO)9]+ leads to [Os3H3(µ3-CH)(CO)9] and [Os3H3(µ3-CCHO)(CO)9] by nucleophilic attack at the α- and β-carbon atoms respectively.

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Article information

DOI
https://doi.org/10.1039/C39860000577
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 577-579

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Nucleophilic addition at the bridging ethynyl ligand in [Os3H(µ-3-C[triple bond, length half m-dash]CH)(CO)9] and hydrolytic cleavage of the carbon–carbon triple bond

E. Boyar, A. J. Deeming and S. E. Kabir, J. Chem. Soc., Chem. Commun., 1986, 577 DOI: 10.1039/C39860000577

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