Synthesis of (+)-1,3,5,7-tetrakis[2-(1S,3S,5R,6S,8R,10R)-D3-trishomocubanylbuta-1,3-diynyl] adamantane. An optically active organic molecule with T symmetry and of known absolute configuration

Masao Nakazaki; Koichiro Naemura; Yukio Hokura

doi:10.1039/C39820001245

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Synthesis of (+)-1,3,5,7-tetrakis[2-(1S,3S,5R,6S,8R,10R)-D₃-trishomocubanylbuta-1,3-diynyl] adamantane. An optically active organic molecule with T symmetry and of known absolute configuration

Masao Nakazaki, Koichiro Naemura and Yukio Hokura

Abstract

Coupling of 1,3,5,7-tetraethynyladamantane (12) with (+)1-bromo-2-[2-(1S,3S,5R,6S,8R,10R)-D₃-trishomocubanyl]ethyne (21) provided the title compound (2) of known absolute configuration whose highest attainable static and time-averaged dynamic symmetry are T and (C₃)⁴∧T, respectively.

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DOI: https://doi.org/10.1039/C39820001245
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1982, 1245-1246

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Synthesis of (+)-1,3,5,7-tetrakis[2-(1S,3S,5R,6S,8R,10R)-D₃-trishomocubanylbuta-1,3-diynyl] adamantane. An optically active organic molecule with T symmetry and of known absolute configuration

M. Nakazaki, K. Naemura and Y. Hokura, J. Chem. Soc., Chem. Commun., 1982, 1245 DOI: 10.1039/C39820001245

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Journal of the Chemical Society, Chemical Communications

Synthesis of (+)-1,3,5,7-tetrakis[2-(1S,3S,5R,6S,8R,10R)-D₃-trishomocubanylbuta-1,3-diynyl] adamantane. An optically active organic molecule with T symmetry and of known absolute configuration

Abstract

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Synthesis of (+)-1,3,5,7-tetrakis[2-(1S,3S,5R,6S,8R,10R)-D₃-trishomocubanylbuta-1,3-diynyl] adamantane. An optically active organic molecule with T symmetry and of known absolute configuration

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