Issue 12, 1980
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis of the carbido anion [Os5C(CO)15I]– and the X-ray crystal structures of Os5C(CO)15 and [(Ph3P)2N][Os5C(CO)15I]

Peter F. Jackson,   Brian F. G. Johnson,   Jack Lewis,   J. Nicola Nicholls,   Mary McPartlin  and  William J. H. Nelson  

Abstract

Os5C(CO)15 has been shown to be isostructural (but not isomorphous) with its iron analogue Fe5C(CO)15 which has a square pyramidal metal geometry and its reaction with iodide gives the anion [Os5C(CO)15I]– in which the osmium atoms have opened out to a bridged butterfly arrangement; the flexibility of the cluster units in reversibility towards electron donation is illustrated.

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Article information

DOI
https://doi.org/10.1039/C39800000564
Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 564-566

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Synthesis of the carbido anion [Os5C(CO)15I]– and the X-ray crystal structures of Os5C(CO)15 and [(Ph3P)2N][Os5C(CO)15I]

P. F. Jackson, B. F. G. Johnson, J. Lewis, J. N. Nicholls, M. McPartlin and W. J. H. Nelson, J. Chem. Soc., Chem. Commun., 1980, 564 DOI: 10.1039/C39800000564

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