In situ fabrication of porous-carbon-supported α-MnO2 nanorods at room temperature: application for rechargeable Li–O2 batteries

Yan Qin; Jun Lu; Peng Du; Zonghai Chen; Yang Ren; Tianpin Wu; Jeffrey T. Miller; Jianguo Wen; Dean J. Miller; Zhengcheng Zhang; Khalil Amine

doi:10.1039/C2EE23621D

In situ fabrication of porous-carbon-supported α-MnO₂nanorods at room temperature: application for rechargeable Li–O₂ batteries†‡

Yan Qin,§^a Jun Lu,§^a Peng Du,^a Zonghai Chen,^a Yang Ren,^b Tianpin Wu,^a Jeffrey T. Miller,^a Jianguo Wen,^c Dean J. Miller,^c Zhengcheng Zhang^a and Khalil Amine*^a

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* Corresponding authors

^a Chemical Science and Engineering Division, Argonne National Laboratory, 9700 South Cass Avenue, Lemont, IL 60439, USA
E-mail: amine@anl.gov
Tel: +1-630-252-3838

^b X-ray Science Division, Advanced Photon Sources, Argonne National Laboratory, 9700 South Cass Avenue, Lemont, IL 60439, USA

^c Electron Microscopy Center, Material Science Division, Argonne National Laboratory, 9700 South Cass Avenue, Lemont, IL 60439, USA

Abstract

Lithium–O₂ cells can be considered the “holy grail” of lithium batteries because they offer much superior theoretical energy density to conventional lithium-ion systems. In this study, porous carbon-supported MnO₂ nanorods synthesized at room temperature were explored as an electrocatalyst for rechargeable Li–O₂ cells. Both high-energy X-ray diffraction and X-ray absorption fine-structure analyses showed that the prepared MnO₂ exhibited a tetragonal crystal structure (α-MnO₂), which has proved to be one of the most efficient catalysts to facilitate the charging of the Li–O₂ cell. Under the current synthetic approach, α-MnO₂ was uniformly distributed onto the surface of a carbon support, without disrupting the porous structure at the surface of the carbon cathode. As a result, the as-prepared catalysts demonstrated good electrochemical behavior, with a capacity of ∼1400 mA h g⁻¹ (carbon + electrocatalyst) under a current density of 100 mA g⁻¹ (carbon + electrocatalyst) during the initial discharge. The charge potential was significantly reduced, to 3.5–3.7 V, compared with most of the reported data, which are above 4.0 V. The mechanism of the capacity fade with cycling was also investigated by analyzing the cathode at different states of discharge–charge by X-ray photoelectron spectroscopy.

Energy & Environmental Science

In situ fabrication of porous-carbon-supported α-MnO₂nanorods at room temperature: application for rechargeable Li–O₂ batteries†‡

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In situ fabrication of porous-carbon-supported α-MnO₂ nanorods at room temperature: application for rechargeable Li–O₂ batteries

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