Highly efficient vinylaromatics generation via iron-catalyzed sp3 C–H bond functionalization CDC reaction: a novel approach to preparing substituted benzo[α]phenazines

Shao-Jie Lou; Dan-Qian Xu; Dan-Feng Shen; Yi-Feng Wang; Yun-Kui Liu; Zhen-Yuan Xu

doi:10.1039/C2CC36708D

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Highly efficient vinylaromatics generation via iron-catalyzed sp³ C–H bond functionalization CDC reaction: a novel approach to preparing substituted benzo[α]phenazines†

Shao-Jie Lou,^a Dan-Qian Xu,*^a Dan-Feng Shen,^a Yi-Feng Wang,^a Yun-Kui Liu^a and Zhen-Yuan Xu*^a

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* Corresponding authors

^a Catalytic Hydrogenation Research Center, State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, P. R. China
E-mail: greenchem@zjut.edu.cn
Fax: +86 571 8832 0066
Tel: +86 571 8832 0066

Abstract

An iron-catalyzed benzylic vinylation was developed to transfer the carbon atom in the N,N-dimethyl moiety of N,N-dimethylacetamide (or N,N-dimethylformamide) to 2-methyl azaarenes to generate 2-vinyl azaarenes.

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Article information

DOI: https://doi.org/10.1039/C2CC36708D
Article type: Communication
Submitted: 14 Sep 2012
Accepted: 25 Oct 2012
First published: 25 Oct 2012

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Chem. Commun., 2012,48, 11993-11995

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Highly efficient vinylaromatics generation via iron-catalyzed sp³ C–H bond functionalization CDC reaction: a novel approach to preparing substituted benzo[α]phenazines

S. Lou, D. Xu, D. Shen, Y. Wang, Y. Liu and Z. Xu, Chem. Commun., 2012, 48, 11993 DOI: 10.1039/C2CC36708D

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