Issue 11, 2011
From the journal:

CrystEngComm

A role for π–Br interactions in the solid-state molecular packing of para-halo-phenoxy-boronsubphthalocyanines†

Andrew S. Paton,a   Alan J. Loughb  and  Timothy P. Bender*ab  

* Corresponding authors

a Department of Chemical Engineering and Applied Chemistry, The University of Toronto, 200 College St., Toronto, Ontario, Canada
E-mail: tim.bender@utoronto.ca

b Department of Chemistry, University of Toronto, 80 St. George St., Toronto, Ontario, Canada

Abstract

We report the synthesis and characterization of a series of para-halo-phenoxy-boronsubphthalocyanines (BsubPcs). Across this series, a crystal polymorph of p-bromophenoxy-BsubPc (α-BrPhO-BsubPc) contains a clear and discernible π–Br interaction directing crystallization into a motif not previously seen for phenoxy-BsubPcs.

Graphical abstract: A role for π–Br interactions in the solid-state molecular packing of para-halo-phenoxy-boronsubphthalocyanines

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Article information

DOI
https://doi.org/10.1039/C0CE00796J
Article type
Communication
Submitted
29 Oct 2010
Accepted
28 Mar 2011
First published
11 Apr 2011

CrystEngComm, 2011,13, 3653-3656

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A role for π–Br interactions in the solid-state molecular packing of para-halo-phenoxy-boronsubphthalocyanines

A. S. Paton, A. J. Lough and T. P. Bender, CrystEngComm, 2011, 13, 3653 DOI: 10.1039/C0CE00796J

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