The nanoscale drum-gong-cymbal-like mixed-valence CuIICuI3cluster polymer and magnetism study

Fang Fang Jian; Li Hua Huang; Bao Xin Huang; Jing Wang; Xian Wang

doi:10.1039/B904818A

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The nanoscale drum-gong-cymbal-like mixed-valence Cu^IICu^I₃cluster polymer and magnetism study†

Fang Fang Jian,*^ab Li Hua Huang,^b Bao Xin Huang,^a Jing Wang^b and Xian Wang^b

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* Corresponding authors

^a Microscale Science Institute, Weifang University, Weifang, P. R. China
E-mail: ffj2003@163169.net

^b New Materials and Function Coordination Chemistry Lab, Qingdao University of Science & Technology, Qingdao, P. R. China
E-mail: wj-crystal@163.com
Fax: +0086-532-84023606

Abstract

The synthesis, structure and magnetic properties of the mixed-valence Cu^ICu^II clusters 1D nano-size tape polymer were reported. The drum-gong-cymbal-like pattern has first been found in this structure. Complex [(phen)₂Cu^II₂Cl₁₀Cu^I₆] forms the most compact stacking mode in the crystal lattice. At very low temperature, the complex exhibits weak ferromagnetic coupling with spin canting antiferromagnetic interactions. The thermal gravity (TG) data indicate that this complex has better thermal stability.

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Article information

DOI: https://doi.org/10.1039/B904818A
Article type: Communication
Submitted: 05 Jan 2009
Accepted: 16 Mar 2009
First published: 31 Mar 2009

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CrystEngComm, 2009,11, 1796-1799

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The nanoscale drum-gong-cymbal-like mixed-valence Cu^IICu^I₃cluster polymer and magnetism study

F. F. Jian, L. H. Huang, B. X. Huang, J. Wang and X. Wang, CrystEngComm, 2009, 11, 1796 DOI: 10.1039/B904818A

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