New fabrication of lanthanide complexes based on the polyoxometalate ligand of the [α(1,4)-GeW10O38]12− anion

YunGao Li; Lin Xu; GuangGang Gao; Ning Jiang; Hong Liu; FengYan Li; YanYan Yang

doi:10.1039/B820269A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

New fabrication of lanthanide complexes based on the polyoxometalate ligand of the [α(1,4)-GeW₁₀O₃₈]¹²⁻ anion†‡§

YunGao Li,^a Lin Xu,*^a GuangGang Gao,^a Ning Jiang,^a Hong Liu,^a FengYan Li^a and YanYan Yang^a

Author affiliations

* Corresponding authors

^a Key Laboratory of Polyoxometalate Science of Ministry of Education, Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin, P. R. China
E-mail: Linxu@nenu.edu.cn

Abstract

New-type two lanthanide complexes based on a germanotungstate ligand, Na₁₂[Ln₄(α(1,4)-GeW₁₀O₃₈)₂ (H₂O)₆]·nH₂O (Ln = Dy (1); Er (2)) which contain four trivalent lanthanide ions and two [α(1,4)-GeW₁₀O₃₈]¹²⁻ units, have been synthesized and structurally characterised, and their magnetic properties have also been investigated. Each lanthanide ion resides in the vacant site of the [α(1,4)-GeW₁₀O₃₈]¹²⁻ fragment through bonding to five oxygen atoms, four of which are from the WO₆ octahedra, while the other one is from the central GeO₄ tetrahedron group.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/B820269A
Article type: Communication
Submitted: 12 Nov 2008
Accepted: 24 Apr 2009
First published: 15 May 2009

Download Citation

CrystEngComm, 2009,11, 1512-1514

Permissions

Request permissions

New fabrication of lanthanide complexes based on the polyoxometalate ligand of the [α(1,4)-GeW₁₀O₃₈]¹²⁻ anion

Y. Li, L. Xu, G. Gao, N. Jiang, H. Liu, F. Li and Y. Yang, CrystEngComm, 2009, 11, 1512 DOI: 10.1039/B820269A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

CrystEngComm