An interwoven Fe3L3 trigonal metallamacrocycle from an in situ ligand hydrolysis reaction

Qing-Fu Zhang; Fei-Long Jiang; You-Gui Huang; Wei Wei; Qiang Gao; Ming Yang; Ke-Cai Xiong; Mao-Chun Hong

doi:10.1039/B817929H

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

An interwoven Fe₃L₃ trigonal metallamacrocycle from an in situligand hydrolysis reaction†

Qing-Fu Zhang,^ab Fei-Long Jiang,^a You-Gui Huang,^a Wei Wei,^ab Qiang Gao,^ab Ming Yang,^ab Ke-Cai Xiong^ab and Mao-Chun Hong*^a

Author affiliations

* Corresponding authors

^a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
E-mail: hmc@fjirsm.ac.cn
Fax: +86 591 8371 4946
Tel: +86 591 8379 2460

^b Graduate School of the Chinese Academy of Sciences, Beijing, China

Abstract

Through an in situhydrolysis reaction of the bishydrazone ligand H₄L1 [H₄L1 = (HOC₆H₄)CH [double bond, length as m-dash] NNHCO(C₅H₃N)CONHNCH(C₆H₄OH)], in the presence of Fe(III) ions, an interwoven trigonal metallamacrocycle [Fe₃L₃(H₂O)₃]·9H₂O (1) [H₃L = (HOC₆H₄)CHNNHCO(C₅H₃N)CO₂H] containing unusually double-layered capsule-like water hexamers was obtained and characterized by elemental analysis, FT-IR, TGA, ESI-MS and X-ray crystallography.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/B817929H
Article type: Communication
Submitted: 13 Oct 2008
Accepted: 08 Dec 2008
First published: 24 Dec 2008

Download Citation

Dalton Trans., 2009, 2673-2676

Permissions

Request permissions

An interwoven Fe₃L₃ trigonal metallamacrocycle from an in situ ligand hydrolysis reaction

Q. Zhang, F. Jiang, Y. Huang, W. Wei, Q. Gao, M. Yang, K. Xiong and M. Hong, Dalton Trans., 2009, 2673 DOI: 10.1039/B817929H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions