A unique chair-shaped hexanuclear Cu(I) metallamacrocyclic C2H4 adduct encapsulating a BF4− anion

Masahiko Maekawa; Atsuhiro Nabei; Toshi Tominaga; Kunihisa Sugimoto; Toshie Minematsu; Takashi Okubo; Takayoshi Kuroda-Sowa; Megumu Munakata; Susumu Kitagawa

doi:10.1039/B812337C

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A unique chair-shaped hexanuclear Cu(I) metallamacrocyclic C₂H₄ adduct encapsulating a BF₄⁻ anion†

Masahiko Maekawa,*^a Atsuhiro Nabei,^b Toshi Tominaga,^b Kunihisa Sugimoto,^c Toshie Minematsu,^d Takashi Okubo,^b Takayoshi Kuroda-Sowa,^b Megumu Munakata^b and Susumu Kitagawa*^ef

Author affiliations

* Corresponding authors

^a Research Institute for Science and Technology, Kinki University, Kowakae, Higashi-Osaka, Osaka, Japan
E-mail: maekawa@rist.kindai.ac.jp

^b Department of Chemistry, Kinki University, Kowakae, Higashi-Osaka, Osaka, Japan

^c Research and Utilization Division, Japan Synchrotron Radiation Research Institute, Kouto, Sayo-cho, Sayo-gun, Hyogo, Japan

^d School of Pharmaceutical Science, Kinki University, Kowakae, Higashi-Osaka, Osaka, Japan

^e Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, Japan
E-mail: kitagawa@sbchem.kyoto-u.ac.jp

^f Institute for Integrated Cell-Material Sciences, Kyoto University, Yoshida, Sakyo-ku, Kyoto, Japan

Abstract

Three novel Cu(I)–C₂H₄ adducts bearing 4-(2-pyridyl)pyrimidine were self-assembled, and the roles of anion and solvent were proved in the formation process.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/B812337C
Article type: Communication
Submitted: 18 Jul 2008
Accepted: 31 Oct 2008
First published: 18 Nov 2008

Download Citation

Dalton Trans., 2009, 415-417

Permissions

Request permissions

A unique chair-shaped hexanuclear Cu(I) metallamacrocyclic C₂H₄ adduct encapsulating a BF₄⁻ anion

M. Maekawa, A. Nabei, T. Tominaga, K. Sugimoto, T. Minematsu, T. Okubo, T. Kuroda-Sowa, M. Munakata and S. Kitagawa, Dalton Trans., 2009, 415 DOI: 10.1039/B812337C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions