Issue 25, 2007
From the journal:

Dalton Transactions

Di-2-pyridyl ketone oxime in copper chemistry: di-, tri-, penta- and hexanuclear complexes†‡

Tereza Afrati,a   Curtis M. Zaleski,c   Catherine Dendrinou-Samara,a   Gellert Mezei,b   Jeff W. Kampf,b   Vincent L. Pecoraro*b  and  Dimitris P. Kessissoglou*a  

* Corresponding authors

a Department of General and Inorganic Chemistry, Aristotle University of Thessaloniki, Thessaloniki, Greece
E-mail: kessisog@chem.auth.gr
Fax: +30-2310-997738
Tel: +30-2310-997723

b Department of Chemistry, University of Michigan, Ann Arbor, MI, USA
E-mail: vlpec@umich.edu
Fax: +1 734-936-7628
Tel: +1 734-763-1519

c Department of Chemistry, Shippensburg University, Shippensburg, PA, USA

Abstract

The use of di-2-pyridyl ketone oxime (Hpko)/X− “blends” (X− = OH−, Cl−, ClO4−) in copper chemistry has yielded neutral binuclear and cationic trinuclear, pentanuclear or hexanuclear complexes. Various synthetic procedures have led to the synthesis of compounds [Cu5(pko)7]·[ClO4]3·2CH3OH·2H2O (1), [Cu3(pko)3(OH)(Cl)]2[Ph4B]2·4DMF·2H2O (2), [Cu2(pko)4] (3), {[Cu6(pko)6ClO4(CH3CN)6][Cu6(pko)6(ClO4)3(CH3CN)4]}·8ClO4·14CH3CN·H2O (4). The structures of the complexes have been determined by single-crystal X-ray crystallography.

Graphical abstract: Di-2-pyridyl ketone oxime in copper chemistry: di-, tri-, penta- and hexanuclear complexes

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Article information

DOI
https://doi.org/10.1039/B700902J
Article type
Paper
Submitted
19 Jan 2007
Accepted
10 Apr 2007
First published
24 Apr 2007

Dalton Trans., 2007, 2658-2668

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Di-2-pyridyl ketone oxime in copper chemistry: di-, tri-, penta- and hexanuclear complexes

T. Afrati, C. M. Zaleski, C. Dendrinou-Samara, G. Mezei, J. W. Kampf, V. L. Pecoraro and D. P. Kessissoglou, Dalton Trans., 2007, 2658 DOI: 10.1039/B700902J

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