Issue 11, 2003
From the journal:

New Journal of Chemistry

Crystal structure and magnetic properties of a new three-dimensional coordination polymer constructed from (4,4) layers based on dimeric iron(ii) subunits

Ming-Hua Zeng,a   Song Gao,b   Xiao-Lan Yua  and  Xiao-Ming Chen*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, China
E-mail: cescxm@zsu.edu.cn

b State Key Laboratory of Rare-Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, China

Abstract

A new metal-organic polymer [Fe(pydc)(H2O)] (1; H2pydc = pyridine-2,5-dicarboxylic acid), has been hydrothermally synthesised and characterised by X-ray diffraction, showing that 1 is a three-dimensional framework featuring two-dimensional carboxylate-bridged layers based on canted dimeric iron(II) subunits. Magnetic measurements demonstrate that, although the carboxylate and pyridyl bridges are present in the layer, 1 exhibits only a weak antiferromagnetism.

Graphical abstract: Crystal structure and magnetic properties of a new three-dimensional coordination polymer constructed from (4,4) layers based on dimeric iron(ii) subunits

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Article information

DOI
https://doi.org/10.1039/B306872B
Article type
Paper
Submitted
16 Jun 2003
Accepted
08 Aug 2003
First published
03 Sep 2003

New J. Chem., 2003,27, 1599-1602

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Crystal structure and magnetic properties of a new three-dimensional coordination polymer constructed from (4,4) layers based on dimeric iron(II) subunits

M. Zeng, S. Gao, X. Yu and X. Chen, New J. Chem., 2003, 27, 1599 DOI: 10.1039/B306872B

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