Issue 5, 2003
From the journal:

Green Chemistry

Development of the continuous-flow reaction system based on the Lewis acid-catalysed reactions in a fluorous biphasic system†

Akihiro Yoshida,a   Xiuhua Haoa  and  Joji Nishikido*a  

* Corresponding authors

a The Noguchi Institute and Japan Chemical Innovation Institute (JCII), Kaga, Tokyo 173-0003, Japan
E-mail: nishikido@noguchi.or.jp
Fax: +81 3 5248 3597
Tel: +81 3 5248 3596

Abstract

Lanthanide(III) bis(perfluoroalkanesulfonyl)amide-catalysed reactions such as esterification and Baeyer–Villiger reactions in organic-fluorous biphase were performed to yield products with high TONs using the continuous-flow system of the small- and bench-scale apparatus which consisted of a reactor with a mechanical stirrer and a decanter. In the novel continuous-flow system, the Lewis acid catalyst is immobilised in a fluorous solvent while the substrates and the products obtained are dissolved in the mobile organic phase.

Graphical abstract: Development of the continuous-flow reaction system based on the Lewis acid-catalysed reactions in a fluorous biphasic system

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Article information

DOI
https://doi.org/10.1039/B304578A
Article type
Paper
Submitted
25 Apr 2003
First published
06 Aug 2003

Green Chem., 2003,5, 554-557

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Development of the continuous-flow reaction system based on the Lewis acid-catalysed reactions in a fluorous biphasic system

A. Yoshida, X. Hao and J. Nishikido, Green Chem., 2003, 5, 554 DOI: 10.1039/B304578A

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