Issue 18, 2002

Aqueous emulsion containing fluorous cobalt species in supercritical CO2 for catalytic air oxidation of toluene

Abstract

An aqueous emulsion containing ionic Co2+ and Br species stabilised by fluorous surfactant-like species in supercritical CO2–air mixture acts as a nano-reactor with excellent interfacial contacts of all necessary hydrophilic/hydrophobic species, which renders safe operation of catalytic aerial oxidation of toluene at high yields.

Graphical abstract: Aqueous emulsion containing fluorous cobalt species in supercritical CO2 for catalytic air oxidation of toluene

Article information

Article type
Communication
Submitted
11 Jun 2002
Accepted
30 Jul 2002
First published
16 Aug 2002

Chem. Commun., 2002, 2044-2045

Aqueous emulsion containing fluorous cobalt species in supercritical CO2 for catalytic air oxidation of toluene

J. Zhu, A. Robertson and S. C. Tsang, Chem. Commun., 2002, 2044 DOI: 10.1039/B205673A

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