Issue 8, 2002
From the journal:

New Journal of Chemistry

Inclusion compounds of binaphthol with volatile guests: structures, selectivity and kinetics of desolvation

Luigi R. Nassimbeni*a  and  Hong Sua  

* Corresponding authors

a Department of Chemistry, University of Cape Town, Rondebosch 7701, South Africa
E-mail: xrayluig@science.uct.ac.za

Abstract

Binaphthol forms inclusion compounds with 1,4-dioxane, morpholine, dimethylsulfoxide, acetone and tetrahydrofuran. The host∶guest ratios of some of these compounds depend on the crystallisation temperature. Competition experiments between pairs of selected guests reveal different kinds of selectivity. Desolvation kinetics for these compounds yield similar activation energies of approximately 80 kJ mol−1.

Graphical abstract: Inclusion compounds of binaphthol with volatile guests: structures, selectivity and kinetics of desolvation

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Article information

DOI
https://doi.org/10.1039/B201255N
Article type
Paper
Submitted
25 Jan 2002
Accepted
18 Apr 2002
First published
28 Jun 2002

New J. Chem., 2002,26, 989-995

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Inclusion compounds of binaphthol with volatile guests: structures, selectivity and kinetics of desolvation

L. R. Nassimbeni and H. Su, New J. Chem., 2002, 26, 989 DOI: 10.1039/B201255N

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