Issue 7, 2002
From the journal:

Chemical Communications

Kinetic isotope effects on the dissolution kinetics of solid salicylic acid in aqueous solution: evidence for solubilisation via a proton dissociation–recombination mechanism†

Shelley J. Wilkins,a   Barry A. Colesa  and  Richard G. Compton*a  

* Corresponding authors

a Physical and Theoretical Chemistry Laboratory, Oxford University, South Parks Road, Oxford, UK
E-mail: richard.compton@chemistry.ox.ac.uk

Abstract

Quantitative Atomic Force Microscopy measurements made on the dissolving surface of solid salicylic acid in H2O and D2O reveal a kinetic isotope effect (kH/kD = 2.3 ± 0.6) on the dissolution rate consistent with a transition state in which the proton is dissociated from the dissolving molecule.

Graphical abstract: Kinetic isotope effects on the dissolution kinetics of solid salicylic acid in aqueous solution: evidence for solubilisation via a proton dissociation–recombination mechanism

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B111642H
Article type
Communication
Submitted
21 Dec 2001
Accepted
18 Feb 2002
First published
05 Mar 2002

Chem. Commun., 2002, 698-699

Permissions

Request permissions

Kinetic isotope effects on the dissolution kinetics of solid salicylic acid in aqueous solution: evidence for solubilisation via a proton dissociation–recombination mechanism

S. J. Wilkins, B. A. Coles and R. G. Compton, Chem. Commun., 2002, 698 DOI: 10.1039/B111642H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements