Issue 15, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

Reactivity of SeOCl2 with titanium and zirconium tetrachlorides. The unexpected formation of a μ-oxo-bridged titanium(IV) derivative

Fausto Calderazzo,a   Michele D’Attoma,a   Fabio Marchettib  and  Guido Pampaloni*a  

* Corresponding authors

a Università di Pisa, Dipartimento di Chimica e Chimica Industriale, Via Risorgimento 35, Pisa, Italy
E-mail: pampa@dcci.unipi.it

b Università di Roma “La Sapienza”, Dipartimento di Ingegneria Chimica, dei Materiali e delle Materie Prime e Metallurgia, Via del Castro Laurenziano 7, Box 15 Roma 62, Roma, Italy

Abstract

The reaction of TiCl4 with SeOCl2 affords the μ-oxo derivative [TiCl3(SeOCl2)2]2(μ-O) through a deoxygenation reaction of SeOCl2 to SeCl4 whereas ZrCl4 gives 1∶1 or 1∶2 adducts of formula ZrCl4(SeOCl2)n, n = 1, 2.

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Article information

DOI
https://doi.org/10.1039/B004057F
Article type
Communication
Submitted
22 May 2000
Accepted
21 Jun 2000
First published
04 Jul 2000

J. Chem. Soc., Dalton Trans., 2000, 2497-2498

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Reactivity of SeOCl2 with titanium and zirconium tetrachlorides. The unexpected formation of a μ-oxo-bridged titanium(IV) derivative

F. Calderazzo, M. D’Attoma, F. Marchetti and G. Pampaloni, J. Chem. Soc., Dalton Trans., 2000, 2497 DOI: 10.1039/B004057F

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