Issue 12, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

Addition of the [(tBuP)3As]− anion to the cyclopentadienyl ring of [(C5H5)M(CO)3Cl] (M = Mo, W)

Alan Bashall,a   Alexander D. Hopkins,b   Martin J. Mays,*b   Mary McPartlin,a   Jody A. Wood,b   Anthony D. Woodsb  and  Dominic S. Wright*b  

* Corresponding authors

a School of Chemistry, University of North London, London, UK

b Chemistry Department, University of Cambridge, Lensfield Road, Cambridge, UK
E-mail: dsw1000@cus.cam.ac.uk

Abstract

Reactions of the [(tBuP)3As]− anion with [(C5H5)M(CO)3Cl] (M = Mo, W) gives [(C5H4{As(PtBu)3})M(CO)3Cl] (M = Mo 1; M = W 2) as a result of addition to the C5H5 ring (with formal elimination of LiH), rather than the expected product resulting from substitution of the metal-bonded Cl ligand.

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Article information

DOI
https://doi.org/10.1039/B003687K
Article type
Communication
Submitted
20 Mar 2000
Accepted
09 May 2000
First published
24 May 2000

J. Chem. Soc., Dalton Trans., 2000, 1825-1826

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Addition of the [(tBuP)3As]− anion to the cyclopentadienyl ring of [(C5H5)M(CO)3Cl] (M = Mo, W)

A. Bashall, A. D. Hopkins, M. J. Mays, M. McPartlin, J. A. Wood, A. D. Woods and D. S. Wright, J. Chem. Soc., Dalton Trans., 2000, 1825 DOI: 10.1039/B003687K

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