Issue 2, 1996
From the journal:

Analyst

Observations on the behaviour of some trifluoroacetophenone derivatives as neutral carriers for carbonate ion-selective electrodes

Tomasz Sokalski,   Dariusz Paradowski,   Joanna Ostaszewska,   Magdalena Maj-Żurawska,   Józef Mieczkowski,   Andrzej Lewenstam  and  Adam Hulanicki  

Abstract

Properties of three derivatives of trifluoacetophenone [4-(n-butyl)-1-trifluoroacetylbenzene (BTFAB), 4-(n-hexadecyl)-1-trifluoroacetylbenzene (HDTFAB), p-dodecyloxytrifluoroacetylbenzene (DDTFAB)] as neutral carriers for carbonate were examined. The best electrode characteristic (slope, S= 29 mV decade–1, lowest detection limit) was for HDTFAB. The sensitivity towards carbonates was for DDTFAB pH dependent. This eliminates DDTFAB from practical applications. A theoretical treatment concerning carbonate and hydrogencarbonate selectivity under investigated conditions has been performed. Preliminary determination of carbonate in bovine serum was made using electrodes with HDTFAB.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/AN9962100133
Article type
Paper

Analyst, 1996,121, 133-138

Permissions

Request permissions

Observations on the behaviour of some trifluoroacetophenone derivatives as neutral carriers for carbonate ion-selective electrodes

T. Sokalski, D. Paradowski, J. Ostaszewska, M. Maj-Żurawska, J. Mieczkowski, A. Lewenstam and A. Hulanicki, Analyst, 1996, 121, 133 DOI: 10.1039/AN9962100133

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements