Issue 3, 2000
From the journal:

New Journal of Chemistry

Intracrystalline reactivity of layered double hydroxides: carboxylate alkylations in dry media

Angel Luis García–Ponce,a   Vanessa Prevot,a   Blanca Casala  and  Eduardo Ruiz–Hitzky*a  

* Corresponding authors

a Instituto de Ciencia de Materiales de Madrid, CSIC, Cantoblanco, Madrid, Spain
E-mail: eduardo@icmm.csic.es

Abstract

This work concerns the reactivity in dry media conditions, i.e. without solvents, of layered double hydroxide (LDH) solids, containing carboxylate ions in their structure, towards alkyl and benzyl halides. Reaction occurs giving the corresponding esters, with excellent yield and selectivity, and preserving the lamellar arrangement of the pristine solids. The reactions were activated by conventional thermal treatment (100 °C) or by microwave (MW) irradiation.

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Article information

DOI
https://doi.org/10.1039/A909263C
Article type
Letter
Submitted
22 Nov 1999
Accepted
23 Dec 1999
First published
22 Feb 2000

New J. Chem., 2000,24, 119-121

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Intracrystalline reactivity of layered double hydroxides: carboxylate alkylations in dry media

A. L. García–Ponce, V. Prevot, B. Casal and E. Ruiz–Hitzky, New J. Chem., 2000, 24, 119 DOI: 10.1039/A909263C

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