Issue 4, 2000
From the journal:

Chemical Communications

[Mo10S10O10(OH)1 0(H2O)5]: a novel decameric molecular ring showing supramolecular properties

Emmanuel Cadot,*a   Bernadette Salignac,a   Jérôme Marrot,a   Anne Dolbecqa  and  Francis Sécheressea  

* Corresponding authors

a Institut Lavoisier. IREM, UMR 8637. Université de Versailles Saint Quentin, 45 Avenue des Etats-Unis, Versailles, France.
E-mail: cadot@chimie.uvsq.fr

Abstract

The new decameric [Mo10S10O10(OH)10(H2 O)5] oxo–thio ring was prepared by self-condensation of [Mo2S2O2]2+ upon addition of hydroxide ion; crystals were obtained in dimethylformamide in the presence of tetrabutylammonium iodide; X-Ray diffraction analysis reveals a 10-membered ring-shaped cluster; the cyclic architecture exhibits a supramolecular assembly resulting from hydrogen bonding between two iodide anions and inner water molecules of the open cavity of the Mo10-ring.

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/A909024J
Article type
Communication
Submitted
15 Nov 1999
Accepted
10 Jan 2000
First published
03 Feb 2000

Chem. Commun., 2000, 261-262

Permissions

Request permissions

[Mo10S10O10(OH)1 0(H2O)5]: a novel decameric molecular ring showing supramolecular properties

E. Cadot, B. Salignac, J. Marrot, A. Dolbecq and F. Sécheresse, Chem. Commun., 2000, 261 DOI: 10.1039/A909024J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements