The [VOCl4]2–/AgOAc reaction system in MeCN gives [V5O9Cl(OAc)4]2–, [V9O19(OAc)5]3– and [V15O36]5– for reagent ratios of 1∶2, 1∶3 and 1∶4, respectively: the V5 and V9 cores are fragments of the V15 core, suggesting the V5 and V9 units are carboxylate-stabilised intermediates in the assembly of the V15 polyoxovanadate.
G. B. Karet, W. E. Streib, J. C. Bollinger, G. Christou, Z. Sun and D. N. Hendrickson, Chem. Commun., 1999, 2249 DOI: 10.1039/A906448F
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