Issue 23, 1997
From the journal:

Journal of the Chemical Society, Faraday Transactions

Free jet investigation of the rotational spectrum of glycerol

Gianni Maccaferri,   Walther Caminati  and  Paolo G. Favero  

Abstract

The microwave spectra (60–78 GHz) of two conformers of jet cooled glycerol have been assigned. They are characterized by three and two intramolecolar hydrogen bonds, (labelled as G′Gg′gg′ and GGtg′g′, respectively). Assuming that no conformational relaxation takes place in the adiabatic expansion, and a Boltzmann distribution of the rotational levels in the jet, the G′Gg′gg′ conformer has been calculated to be the more stable by 2.6(6) kJ mol-1.

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Article information

DOI
https://doi.org/10.1039/A705645A
Article type
Paper

J. Chem. Soc., Faraday Trans., 1997,93, 4115-4117

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Free jet investigation of the rotational spectrum of glycerol

G. Maccaferri, W. Caminati and P. G. Favero, J. Chem. Soc., Faraday Trans., 1997, 93, 4115 DOI: 10.1039/A705645A

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