Radical species produced from the photolytic and pulse-radiolytic degradation of tert-butyl hydroperoxide. An EPR spin trapping investigation
Abstract
The radicals generated during the photolysis of tert-butyl hydroperoxide have been identified by comparison with those generated by reductive pulse radiolysis of the same compound, by photolysis of di-tert-butyl peroxide, and by oxidative degradation of dimethyl sulfoxide. While ButO˙ can definitely be identified as the primary alkoxyl radical intermediate, the identify of the predominantly-formed peroxyl radical is dependent on the generation system.
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