A stable metal azolate framework with rare nonintersecting one-/two-dimensional pore channels†
Dong-Dong
Zhou 
*a
and
Jie-Peng
Zhang
a
*a
and
Jie-Peng
Zhang
a
Abstract
It is challenging to design and synthesize stable crystalline structures with heterogeneous pores. Herein, we design and synthesize a new azole ligand with rich aromatic moieties and trifluoromethyl groups, and construct a new stable metal azolate framework, which possesses a special three-dimensional (3D) framework with rare nonintersecting 1D/2D pore channels.
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