Strain in a platinum plate induced by an ultrahigh energy laser boosts the hydrogen evolution reaction†
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Abstract
The ligand and the strain near the active sites in catalysts jointly affect the electrocatalytic activity for the catalytic industry. In many cases, there is no effective strategy for the independent study of the strain effect without the ligand effect on the electrocatalytic activity for the hydrogen evolution reaction (HER). Laser shock peening (LSP) with a GW cm−2 level power density and a 10–30 ns short pulse is employed to form compressive strain on the surface and in the depth direction of a platinum (Pt) plate, which changes the inherent interatomic distance and modifies the energy level of the bonded electrons, thereby greatly optimizing the energy barrier for the HER. The crystal lattice near the surface of the LSP Pt plate is distorted by the strain, and the interplanar spacing decreases from 0.225 nm in the undeformed region to 0.211 nm in the deformed region. The specific activity of the LSP Pt has an increase of 2.9 and 6.4 times in comparison with that of the pristine Pt in alkaline and acidic environments, respectively. This investigation provides a novel strategy for the independent study of the strain effect on the electrocatalytic activity and the improvement of electrocatalysts with high performance in extensive energy conversion.
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