Issue 84, 2015

Preparation of dipyrrins from F-BODIPYs by treatment with methanesulfonic acids

Abstract

An alternative metal-free soft procedure for the preparation of dipyrrins from F-BODIPYs is reported. The new method makes possible to obtain certain dipyrrin derivatives that were unaccessible from F-BODIPYs to date. To demonstrate the ability of the new procedure, dipyrrins having highly reactive groups, such as chloro, cyano or acetoxyl, have been easily obtained from the corresponding F-BODIPY, which shows the synthetic utility of the reported methodology.

Graphical abstract: Preparation of dipyrrins from F-BODIPYs by treatment with methanesulfonic acids

Supplementary files

Article information

Article type
Paper
Submitted
27 Jul 2015
Accepted
03 Aug 2015
First published
03 Aug 2015

RSC Adv., 2015,5, 68676-68680

Author version available

Preparation of dipyrrins from F-BODIPYs by treatment with methanesulfonic acids

J. Urieta, B. L. Maroto, F. Moreno, A. R. Agarrabeitia, M. J. Ortiz and S. de la Moya, RSC Adv., 2015, 5, 68676 DOI: 10.1039/C5RA14914B

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