Issue 80, 2015
From the journal:

Chemical Communications

A hierarchically core/shell-structured titanosilicate with multiple mesopore systems for highly efficient epoxidation of alkenes†

Chen-Geng Li,a   Yiqun Lu,a   Haihong Wu,a   Peng Wu*a  and  Mingyuan He*a  

* Corresponding authors

a Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, North Zhongshan Road 3663, Shanghai, China
E-mail: pwu@chem.ecnu.edu.cn, hemingyuan@126.com

Abstract

A hierarchical titanosilicate, with epitaxially grown MFI nanosheets on microsized TS-1 crystals, has been prepared through a desilication–recrystallization method using a diammonium surfactant as the secondary structure-directing agent (SDA). This core/shell material features multiple mesoporosities, significantly improved epoxidation activity as well as easy separation in synthesis and catalytic reactions.

Graphical abstract: A hierarchically core/shell-structured titanosilicate with multiple mesopore systems for highly efficient epoxidation of alkenes

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Article information

DOI
https://doi.org/10.1039/C5CC05278E
Article type
Communication
Submitted
27 Jun 2015
Accepted
18 Aug 2015
First published
18 Aug 2015

Chem. Commun., 2015,51, 14905-14908

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A hierarchically core/shell-structured titanosilicate with multiple mesopore systems for highly efficient epoxidation of alkenes

C. Li, Y. Lu, H. Wu, P. Wu and M. He, Chem. Commun., 2015, 51, 14905 DOI: 10.1039/C5CC05278E

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