Issue 17, 2014

Formation, self-assembly and transformation of a transient selenotungstate building block into clusters, chains and macrocycles

Abstract

The one-pot syntheses of a series of dimeric and trimeric selenotungstates based on the [Se2W12O46]12− unit are presented alongside the structure of the tetrameric [Se8W48O176]32− wheel. Mass spectrometry has probed the stability of these clusters whilst their electronic structure has been contrasted to their known phosphotungstate analogues.

Graphical abstract: Formation, self-assembly and transformation of a transient selenotungstate building block into clusters, chains and macrocycles

Supplementary files

Article information

Article type
Communication
Submitted
06 Dec 2013
Accepted
03 Jan 2014
First published
06 Jan 2014

Chem. Commun., 2014,50, 2155-2157

Author version available

Formation, self-assembly and transformation of a transient selenotungstate building block into clusters, chains and macrocycles

J. M. Cameron, J. Gao, L. Vilà-Nadal, D. Long and L. Cronin, Chem. Commun., 2014, 50, 2155 DOI: 10.1039/C3CC49293A

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