Issue 21, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and structural characterisation of two novel GdIIIβ-diketonates [Gd4(µ3-OH)4(µ2-H2O)2(H2O)4(hfpd)8]·2C6H6·H2O 1 and [Gd(hfpd)3(Me2CO)(H2O)] 2(hfpd–H = 1,1,1,5,5,5-hexafluoropentane-2,4-dione)

John C. Plakatouras,   Ian Baxter,   Michael B. Hursthouse,   K. M. Abdul Malik,   John McAleese  and  Simon R. Drake  

Abstract

Two novel GdIII–hfpd complexes 1 and 2 have been synthesised from aqueous and non-aqueous media; the crystal structural studies reveal that 1 has a M4O6 bicapped cubane core with the metals having tricapped trigonal prismatic geometry, while 2 is a monomeric adduct with water and acetone in the coordination sphere, with the metal having square antiprismatic geometry.

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Article information

DOI
https://doi.org/10.1039/C39940002455
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 2455-2456

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Synthesis and structural characterisation of two novel GdIIIβ-diketonates [Gd4(µ3-OH)4(µ2-H2O)2(H2O)4(hfpd)8]·2C6H6·H2O 1 and [Gd(hfpd)3(Me2CO)(H2O)] 2(hfpd–H = 1,1,1,5,5,5-hexafluoropentane-2,4-dione)

J. C. Plakatouras, I. Baxter, M. B. Hursthouse, K. M. A. Malik, J. McAleese and S. R. Drake, J. Chem. Soc., Chem. Commun., 1994, 2455 DOI: 10.1039/C39940002455

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