Issue 22, 1981

α-C-Glycopyranosides from Lewis acid catalysed condensations of acetylated glycals and enol silanes

Abstract

Acetylated glycals undrgo Lewis acid-catalysed condensations with enol silanes in virtually quantitative yields to form C-glycopyranosides in which the termo-dynamically unfavourable α-‘anomers’ are formed predominantly.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 1180-1181

α-C-Glycopyranosides from Lewis acid catalysed condensations of acetylated glycals and enol silanes

R. D. Dawe and B. Fraser-Reid, J. Chem. Soc., Chem. Commun., 1981, 1180 DOI: 10.1039/C39810001180

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