Issue 7, 1980

High co-ordination numbers for methylmercury(II); X-ray and 1H n.m.r. studies of [MeHgL]NO3(L = 4,4′,4″-triethyl-2,2′:6′,2″-terpyridyl and di-2-pyridylmethane)

Abstract

Methylmercury(II) forms complexes [MeHgL]NO3(L = 2,2′:6′,2″-terpyridyls and di-2-pyridylmethane) where the ligands L are bidentate in methanol, but tridentate and bidentate, respectively, in the solid state with co-ordination geometries for mercury based on a near linear dominant C–Hg–N unit with additional weak Hg–N bonding.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 316-318

High co-ordination numbers for methylmercury(II); X-ray and 1H n.m.r. studies of [MeHgL]NO3(L = 4,4′,4″-triethyl-2,2′:6′,2″-terpyridyl and di-2-pyridylmethane)

A. J. Canty, G. Hayhurst, N. Chaichit and B. M. Gatehouse, J. Chem. Soc., Chem. Commun., 1980, 316 DOI: 10.1039/C39800000316

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