A new procedure for reducing a phosphinate (LO) into the corresponding phosphinite (L) includes the following steps: LO → LS → CpNi(I)L → NiL4→ L (Cp = cyclopentadiene); such a scheme is illustrated by the syntheses of 2-phenyl-1,2-oxaphospholane and 2-phenylisophosphindoline 2-oxide.
F. Mathey and F. Mercier, J. Chem. Soc., Chem. Commun., 1980, 191 DOI: 10.1039/C39800000191
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