Issue 22, 1978

Formation of nona(ethyl isocyanide)di-iron from penta(ethyl isocyanide)iron and reaction of penta(t-butyl isocyanide)iron with diphenylacetylene; X-ray crystal structures of nona(ethyl isocyanide)di-iron and tris(t-butyl isocyanide){1,4-bis-(t-butylimino)-2,3-diphenylbuta-1,3-diene}iron

Abstract

U.v. irradiation of [Fe(CNEt)5] in diethyl ether affords [Fe2(CNEt)9], and reaction of diphenylacetylene with [Fe(CNBut)5] gives [Fe(CNBut)3{1–4-η-ButN[double bond, length half m-dash]C[double bond, length half m-dash]C(Ph)C(Ph)[double bond, length half m-dash]C[double bond, length half m-dash]NBut}]; the molecular structures of these complexes are established by single crystal X-ray crystallography.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1978, 1000-1001

Formation of nona(ethyl isocyanide)di-iron from penta(ethyl isocyanide)iron and reaction of penta(t-butyl isocyanide)iron with diphenylacetylene; X-ray crystal structures of nona(ethyl isocyanide)di-iron and tris(t-butyl isocyanide){1,4-bis-(t-butylimino)-2,3-diphenylbuta-1,3-diene}iron

J. Bassett, M. Green, J. A. K. Howard and F. G. A. Stone, J. Chem. Soc., Chem. Commun., 1978, 1000 DOI: 10.1039/C39780001000

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