The (3R)- and (3S)-forms of [3-3H]tryptophan have been synthesised by the oxazolinone method and used to show that side-chain hydroxylation in the bio-synthesis of sporidesmin A takes place with retention of configuration at the site of attack.
G. W. Kirby and M. J. Varley, J. Chem. Soc., Chem. Commun., 1974, 833 DOI: 10.1039/C39740000833
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