Issue 5, 2009
From the journal:

Dalton Transactions

2,2′:6′,2″-Terpyridine meets 2,6-bis(1H-1,2,3-triazol-4-yl)pyridine: tuning the electro-optical properties of ruthenium(ii) complexes†

Benjamin Schulze,ab   Christian Friebe,ab   Martin D. Hager,b   Andreas Winter,b   Richard Hoogenboom,b   Helmar Görlsc  and  Ulrich S. Schubert*ab  

* Corresponding authors

a Friedrich-Schiller-University Jena, Laboratory of Organic and Macromolecular Chemistry, Humboldtstr. 10, 07743 Jena, Germany

b Eindhoven University of Technology, Laboratory of Macromolecular Chemistry and Nanoscience, P.O. Box 513, 5600 MB Eindhoven, The Netherlands
E-mail: u.s.schubert@tue.nl
Fax: +31 40 2474186
Tel: +31 40 2475303

c Friedrich-Schiller-University Jena, Laboratory of Inorganic and Analytic Chemistry, Lessing-Str. 8, 07743 Jena, Germany

Abstract

The synthesis of a series of heteroleptic ruthenium(II)-complexes containing both, 2,2′:6′,2″-terpyridine and 2,6-bis(1H-1,2,3-triazol-4-yl)pyridine, is reported for the first time. The provided complexes feature photophysical and electrochemical properties in between those known for the respective homoleptic complexes. The flexibility with respect to lateral functional groups to be introduced into the complexes underlines the high potential for further functionalization steps.

Graphical abstract: 2,2′:6′,2″-Terpyridine meets 2,6-bis(1H-1,2,3-triazol-4-yl)pyridine: tuning the electro-optical properties of ruthenium(ii) complexes

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Article information

DOI
https://doi.org/10.1039/B813925C
Article type
Paper
Submitted
11 Aug 2008
Accepted
30 Sep 2008
First published
21 Nov 2008

Dalton Trans., 2009, 787-794

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2,2′:6′,2″-Terpyridine meets 2,6-bis(1H-1,2,3-triazol-4-yl)pyridine: tuning the electro-optical properties of ruthenium(II) complexes

B. Schulze, C. Friebe, M. D. Hager, A. Winter, R. Hoogenboom, H. Görls and U. S. Schubert, Dalton Trans., 2009, 787 DOI: 10.1039/B813925C

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