Issue 17, 2004
From the journal:

Chemical Communications

Palladium catalysed cross-coupling reactions of silylamines†‡

Catherine J. Smith,*a   Tessa R. Early,a   Andrew B. Holmes*a  and  Richard E. Shuteb  

* Corresponding authors

a Melville Laboratory for Polymer Synthesis, Department of Chemistry, Lensfield Road, Cambridge, UK
E-mail: abh1@cam.ac.uk
Fax: +44 1223 334866;
Tel: +44 1223 334370

b AstraZeneca Research and Development, Alderley Park, Macclesfield, Cheshire, UK

Abstract

The palladium-catalysed formation of C–N bonds to produce a range of aryl amines in supercritical carbon dioxide is reported; carbamic acid formation is avoided in part by the use of N-silylamines as surrogates for the free amine.

Graphical abstract: Palladium catalysed cross-coupling reactions of silylamines

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Article information

DOI
https://doi.org/10.1039/B406868H
Article type
Communication
Submitted
07 May 2004
Accepted
26 May 2004
First published
09 Jul 2004

Chem. Commun., 2004, 1976-1977

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Palladium catalysed cross-coupling reactions of silylamines

C. J. Smith, T. R. Early, A. B. Holmes and R. E. Shute, Chem. Commun., 2004, 1976 DOI: 10.1039/B406868H

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