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DUAL CATALYSIS

Golden potential

Nature Chemistry volume 11, pages 760–761 (2019)Cite this article

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Due to the high oxidation potential of gold, the development of dual gold/photoredox-catalysed processes has been limited by the need for an easily reduced radical source. Now, discovery of an energy transfer photoexcitation process overcomes this limitation, enabling the oxidative addition of iodoalkynes onto organogold intermediates.

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Fig. 1: Mechanism of the dual gold- and photoredox-catalysed cross-coupling reaction.

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  1. Institute of Chemical Sciences, Heriot-Watt University, Edinburgh, UK

    Euan B. McLean & Ai-Lan Lee

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  1. Euan B. McLean
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  2. Ai-Lan Lee
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Correspondence to Ai-Lan Lee.

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McLean, E.B., Lee, AL. Golden potential. Nat. Chem. 11, 760–761 (2019). https://doi.org/10.1038/s41557-019-0315-9

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