Abstract
IDENTIFICATION and characterization of mixtures of sugars by gas–liquid chromatography (GLC) have posed considerable difficulty since the advent of the technique1,2. The principal problems have been: (a) the isomerism of the sugars, giving several peaks for each sugar, and (b) the lack of sugar derivatives with sufficient volatility and stability to avoid overlong retention times and degradation during chromatographic separation.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Wells, W. W., Sweeley, C. C., and Bentley, R., in Biomedical Application of Gas Chromatography (edit. by Szymanski, H. A.), 169 (Plenum Press, New York, 1964).
Berry, J. W., in Advances in Chromatography, 11 (edit. by Giddings, J. C., and Keller, R. A.), 271 (M. Dekker, New York, 1966).
Bishop, C. T., in Advances in Carbohydrate Chemistry, 19 (edit. by Wolfrom. M. L.), 95 (Academic Press, New York, 1964).
Sweeley, C. C., Bentley, R., Makita, M., and Wells, W. W., J. Amer. Chem. Soc., 85, 2497 (1962).
Abdel-Akher, M., Hamilton, J. K., and Smith, F., J. Amer. Chem. Soc., 73, 4691 (1951).
Sarwardeker, J. S., Sloneker, J. H., and Jeanes, A., Anal. Chem. 37, 1602 (1965).
Oades, J. M., J. Chromatog., 28, 246 (1967).
Lehnhardt, W. F., and Winzler, R. J., J. Chromatog., 34, 471 (1968).
Horning, E. C., and VandenHeuvel, W. J. A., in Advances in Chromatography, 1 (edit. by Giddings, J. C., and Keller, R. A.), 153 (M. Dekker, New York, 1965).
Gehrke, C. W., and Stalling, D. L., in Separation Techniques in Chemistry and biochemistry (edit. by Keller, R. A.), 21 (M. Dekker, New York, 1967).
Vilkas, M., Hin-I-Jan, Boussac, M., and Bonnard, M., Tetrahedron Lett., 14, 1441 (1966).
Tamura, Z., and Imanari, T., Chem. Pharm. Bull., 15, 246 (1967).
VandenHeuvel, W. J. A., Haahti, E. O. A., and Horning, E. O., J. Amer. Chem. Soc., 83, 1513 (1961).
Lohmar, R. L., in The Carbohydrates (edit. by Pigman, W.), 241 (Academic Press, New York, 1957).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
SHAPIRA, J. Identification of Sugars as their Trifluoroacetyl Polyol Derivatives. Nature 222, 792–793 (1969). https://doi.org/10.1038/222792a0
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1038/222792a0
This article is cited by
-
Structural Features and Anti-coagulant Activity of the Sulphated Polysaccharide SPS-CF from a Green Alga Capsosiphon fulvescens
Marine Biotechnology (2015)
-
Lignin-carbohydrate bonds in a residual soda spruce pulp lignin
Wood Science and Technology (1994)
-
Zur Isolierung von Hemicellulosen desd-xylantyps aus Laubhölzern
Holz als Roh- und Werkstoff (1986)
-
Chemical composition and structure of cell wall teichoic acids of staphylococci
Archives of Microbiology (1983)
-
Identification of the monosaccharides of triterpene glycosides in the form of polyol trifluoroacetates
Chemistry of Natural Compounds (1972)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.