Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Letter
  • Published:

The Elovich Equation in Chemisorption Kinetics

Abstract

THE equation first proposed by Roginsky and Zeldovich1 but now generally known as the Elovich equation has been extensively applied to chemisorption data2,3. The equation is where q = amount of gas chemisorbed at time t and a and α are constants.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Similar content being viewed by others

References

  1. Roginsky, S. Z., and Zeldovich, J., Acta Physicochim. USSR, 1, 554 (1934).

    Google Scholar 

  2. Low, M. J. D., Chem. Rev., 60, 267 (1960).

    Article  CAS  Google Scholar 

  3. Taylor, G. A., and Thon, N., J. Amer. Chem. Soc., 74, 4169 (1952).

    Article  CAS  Google Scholar 

  4. Cimino, A., Molinari, E., and Cipollini, E., Actes Second Intern. Congr. Catalysis, Paris 1960, 1, 263 (Edition Technip, Paris, 1961).

    Google Scholar 

  5. McLintock, I. S., and Ritchie, M., Trans. Farad. Soc., 61, 1007 (1965).

    Article  CAS  Google Scholar 

  6. Deitz, V. R., and McFarlane, E. F., Proc. Fifth Carbon Conf., 2, 219 (Pergamon Press, 1962).

    Google Scholar 

  7. Fraser, J. C. W., and Heard, L., J. Phys. Chem., 42, 855 (1938).

    Article  Google Scholar 

  8. Burwell, R. L., and Taylor, H. S., J. Amer. Chem. Soc., 58, 697 (1936).

    Article  CAS  Google Scholar 

  9. Connor, P., Lewis, J. B., and Thomas, W. J., Proc. Fifth Carbon Conf., 1, 120 (Pergamon Press, 1962).

    Article  CAS  Google Scholar 

  10. Uhlig, H. H., Pickett, J., and Macnairn, J., Acta Metallurgica, 7, 111 (1959).

    Article  CAS  Google Scholar 

  11. Brunauer, S., and Emmett, P. H., J. Amer. Chem. Soc., 56, 35 (1935).

    Google Scholar 

  12. Charman, H. B., and Dell, R. M., Trans. Farad. Soc., 59, 453, 470 (1965).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

MCLINTOCK, I. The Elovich Equation in Chemisorption Kinetics. Nature 216, 1204–1205 (1967). https://doi.org/10.1038/2161204a0

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1038/2161204a0

This article is cited by

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing