Abstract
Bernal and Hockings1 have recently deduced from electron spin resonance data that the pentacyanonitro-sylferrate (I) anion should be considered as a molecular species with the unpaired electron delocalized between the metal and the nitrogen atom of the NO+ group. This work has now been extended, and results presented here show to what extent the electron is delocalized.
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References
Bernal, I., and Hockings, E. F., Proc. Chem. Soc., 361 (1962).
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RAYNOR, J. Electron Spin Resonance Spectrum of the Pentacyanonitrosylferrate (I) Anion. Nature 201, 1216–1217 (1964). https://doi.org/10.1038/2011216a0
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DOI: https://doi.org/10.1038/2011216a0
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