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Relation of the Globular to the Fibrous Form of Silk Fibroin

Abstract

WE have recently stated that if silk II (for example, silk of the cocoon filament1) is treated with hot alkali, there appears in X-ray diagrams at the equator one reflexion of 45 A., besides some additional higher orders (silk III2). Diagrams of higher-orientated samples show that the net plane with D= 45 A. coincides with the equator reflexions (D= 9.15 and 4.57 A.), which, as is well known, represent the plane of the flat micelles. The 45-A. reflexion is much more intense and sharp than the equator reflexions of 9.15 and 4.57 A.

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References

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KRATKY, O., SCHAUENSTEIN, E., SEKORA, A. et al. Relation of the Globular to the Fibrous Form of Silk Fibroin. Nature 167, 861–862 (1951). https://doi.org/10.1038/167861a0

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