Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Letter
  • Published:

Charge states of the vacancy in diamond

Abstract

KNOWLEDGE of radiation damage processes in diamond has increased substantially in the past few years. I present here a concise summary of these data, and suggest that the 25,410 cm−1 (ND1) absorption band occurs at a negatively charged vacancy. It will be shown that with this interpretation, the optical effects of radiation damage fall into a self-consistent pattern.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Similar content being viewed by others

References

  1. Clark, C. D., Ditchburn, R. W. & Dyer, H. B. Proc. R. Soc. A234, 361 (1956).

    Google Scholar 

  2. Davies, G. & Lightowlers, E. C. J. Phys. C3, 638 (1970).

    CAS  ADS  Google Scholar 

  3. Walker, J., Vermeulen, L. A. & Clark, C. D. Proc. R. Soc. A341, 253 (1974).

    CAS  ADS  Google Scholar 

  4. Clark, C. D. & Walker, J. Proc. R. Soc. A334, 241 (1973).

    CAS  ADS  Google Scholar 

  5. Davies, G. & Penchina, C. M. Proc. R. Soc. A338, 359 (1974).

    CAS  ADS  Google Scholar 

  6. Palmer, D. W. thesis, Univ. Reading (1961).

  7. Mitchell, E. W. J. in Science and Technology of Industrial Diamonds 1, 17 (Industrial Diamond Information Bureau, London, 1967).

    Google Scholar 

  8. Norris, G. B., Brower, K. L. & Vook, F. L. Rad. Effects 18, 1 (1973).

    Article  Google Scholar 

  9. Hiraki, A., Cleland, J. W. & Crawford, J. H. J. appl. Phys. 38, 3519 (1967).

    Article  CAS  ADS  Google Scholar 

  10. Clark, G. D., Duncan, I., Lomer, J. N. & Whippey, P. W. Proc. Br. ceram. Soc. 1, 85 (1964).

    Google Scholar 

  11. Coulson, C. A. & Kearsley, M. J. Proc. R. Soc. A241, 433 (1957).

    CAS  ADS  Google Scholar 

  12. Yamaguchi, T. J. phys. Soc. (Japan) 17, 1359 (1962).

    Article  CAS  ADS  Google Scholar 

  13. Coulson, C. A. & Larkins, F. P. J. phys. Chem. Solids 32, 2245 (1971).

    Article  CAS  ADS  Google Scholar 

  14. Rouhani, M. D., Lannoo, M. & Lenglert, P. J. Phys. (France) 31, 597 (1970).

    Article  Google Scholar 

  15. Messmer, R. P. & Watkins, G. D. in Radiation Effects in Semiconductors (eds Corkett, J. W. & Watkins, G. D.) 23 (Gordon and Breach, London, 1971).

    Google Scholar 

  16. Farrer, R. G. Solid St. Commun. 7, 685 (1969).

    Article  CAS  ADS  Google Scholar 

  17. Dyer, H. B. & du Preez, L. J. chem. Phys. 42, 1898 (1965).

    Article  CAS  ADS  Google Scholar 

  18. Davies, G. Chemistry and Physics of Carbon (eds Philips, P. W. & Turner, P. A.) 13, 1 (Dekker, New York, 1977).

    Google Scholar 

  19. Farrer, R. G. & Vermeulen, L. A. J. Phys. C5, 2762 (1972).

    CAS  ADS  Google Scholar 

  20. Vermeulen, L. A., Clark, C. D. & Walker, J. Proc. Freiburg Conf. 294 (Conf. Ser. no. 21 Institute of Physics, London, 1974).

  21. Clark, C. D., Ditchburn, R. W. & Dyer, H. B. Proc. R. Soc. A237, 75 (1956).

    CAS  ADS  Google Scholar 

  22. du Preez, L. thesis, Univ. Witwatersrand, (1965).

  23. Davies, G. & Hamer, M. F. Proc. R. Soc. A348, 285 (1976).

    CAS  ADS  Google Scholar 

  24. Loubser, J. H. N. & van Wyk, J. A. Diamond Research 1977 11 (de Beers Industrial Diamond Div. Pty Ltd, Ascot, 1977).

    Google Scholar 

  25. Davies, G. J. Phys. C9, L537 (1976).

    CAS  ADS  Google Scholar 

  26. Burton, B. thesis, Univ. London (1976).

  27. Vermeulen, L. A. Diamond Research 22 (Industrial Diamond Information Bureau, Ascot, 1976).

    Google Scholar 

  28. Watkins, G. D. in Defects and their Structure in Nonmetallic Solids (eds Henderson, B. & Hughes, A. E.) 203 (Plenum, New York, 1976).

    Book  Google Scholar 

  29. Lomer, J. N. & Welbourn, C. M. Diamond Research 5 (de Beers Industrial Diamond Div. Pty Ltd, Ascot, 1977).

    Google Scholar 

  30. Walker, J., J. Phys. (in the press).

  31. Davies, G. Diamond Conference, Reading (1977).

  32. de Sa, E. S. & Davies, G. Proc. R. Soc. (in the press).

  33. Walker, J. Inst. Phys. Conf. Series no. 23, 317 (1975).

  34. Davies, G., Nazarć, M. H. & Hamer, M. F. Proc. R. Soc. A351, 245 (1976).

    CAS  ADS  Google Scholar 

  35. Kaplyanskii, A. A., Kolyshkin, V. I. & Medvedev, V. N. Sov. Phys. Solid St. 12, 1193 (1970).

    Google Scholar 

  36. Dyer, H. B. & Ferdinando, P. Br. J. appl. Phys. 17, 419 (1966).

    Article  CAS  ADS  Google Scholar 

  37. Davies, G. Proc. R. Soc. A336, 507 (1974).

    CAS  ADS  Google Scholar 

  38. Davies, G. J. Phys. C3, 2474 (1970).

    CAS  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

DAVIES, G. Charge states of the vacancy in diamond. Nature 269, 498–500 (1977). https://doi.org/10.1038/269498a0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1038/269498a0

This article is cited by

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing