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Reactions involving singlet oxygen and the superoxide anion

A Corrigendum to this article was published on 11 November 1976

Abstract

IN discussing reactions involving the superoxide anion O2, it is generally considered that the radical itself or singlet oxygen generated from O2 is harmful to molecules of biological importance1,2. Since the demonstration that singlet oxygen participates in reactions is technically difficult, conclusions about its effects are rather speculative. I show here, on thermo-dynamic grounds, in which reactions singlet oxygen can be formed from O2 and in which reactions this is improbable.

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KOPPENOL, W. Reactions involving singlet oxygen and the superoxide anion. Nature 262, 420–421 (1976). https://doi.org/10.1038/262420a0

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