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Mössbauer and X-ray crystallographic studies of etraalkylammonium hexacyanoferrates(III)

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Abstract

A hexacyanoferrate(III) salt [N(C2H5)4]3[Fe(CN)6].5H2O (1)crystallized in a monoclinic space group (P21, Z = 2) with the nearest neighboring Fe-Fe distance of 8.20 Åound 1 distinctly showed magnetically-relaxed 57Fe Mössbauer spectra below ca. 40 K. The Mössbauer line width at 4.2 K was much larger than that of K3[Fe(CN)6], which is ascribable to the long Fe-Fe distance in 1. Further broadened spectra were observed for [N(n-C4H9)4]3[Fe(CN)6].xH2O (2).

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Authors and Affiliations

  1. National Institute of Advanced Industrial Science and Technology, Tsukuba Central 6, Tsukuba, Ibaraki, 305-8566, Japan

    S. Iijima, F. Mizutani & M. Sato

  2. Department of Materials Science, Chemical Analysis Center, Saitama University, Shimo-Okubo, Urawa, Saitama, 338-8570, Japan

    M. Watanabe

Authors
  1. S. Iijima
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  2. F. Mizutani
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  3. M. Watanabe
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  4. M. Sato
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Iijima, S., Mizutani, F., Watanabe, M. et al. Mössbauer and X-ray crystallographic studies of etraalkylammonium hexacyanoferrates(III). Journal of Radioanalytical and Nuclear Chemistry 255, 503–508 (2003). https://doi.org/10.1023/A:1022528314990

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