Abstract
Coordination compounds of thiourea with cadmium(II), zinc(II), bismuth(III), and indium(III) nitrates were synthesized. The self-sustained combustion of these complexes, as well as that of thiosemicarbazide coordination compounds of nickel(II), cobalt(II), iron(II), copper(II), lead(II), and zinc(II) nitrates, was studied in an inert atmosphere. All these compounds burn to yield metal sulfides. The particle size and morphology of the product depend on the pressure at which the process is carried out. For cadmium(II) and zinc(II) sulfides, which are capable of subliming at the combustion temperatures of their precursors, these parameters can be varied in wide ranges.
Similar content being viewed by others
REFERENCES
Gorbunov, V.V., Shidlovskii, A.A., and Shmagin, L.F., Combustion of Copper(II), Nickel(II), and Cobalt(III) Ammine Complexes with Perchlorate and Nitrate Anions, Fiz. Goreniya Vzryva, 1971, vol. 7, no. 4, pp. 607–609.
Gorbunov, V.V. and Shmagin, L.F., Combustion of Tetraamminecopper( II) Salts, Fiz. Goreniya Vzryva, 1972, vol. 8, no. 4, pp. 523–526.
Shidlovskii, A.A., Gorbunov, V.V., and Shmagin, L.F., Combustion of Transition-Metal Ammine and Hydrazine Complexes with Picrate, Styphnate, and Nitrate Anions, Izv. Vyssh. Uchebn. Zaved., 1978, vol. 21, no. 9, pp. 1249–1251.
Gorbunov, V.V., Shidlovskii, A.A., and Shmagin, L.F., Combustion of Transition-Metal Ethylenediamine Complexes with Nitrate Anions, Fiz. Goreniya Vzryva, 1983, vol. 19, no. 2, pp. 46–47.
Sinditsky, V.P., Fogelzang, A.E., Egorshev, V.Y., et al., Catalysis and Combustion Mechanism of Coordination Compounds, Proc. 21st Int. Pyrotechnical Sem., Moscow, 1995, pp. 747–761.
Sinditskii, V.P. and Fogel'zang, A.E., Energy-Rich Materials Based on Coordination Compounds, Ross. Khim.Zh., 1997, vol. 41, no. 4, pp. 74–80.
Gavrilov, A.I., Tukhtaev, R.K., Larionov, S.V., et al., Preparation of Fine-Particle Nickel with Controlled Morphology by Combustion, Dokl. Akad. Nauk, 1996, vol. 348, no. 2, pp. 201–204.
Tukhtaev, R.K., Gavrilov, A.I., Larionov, S.V., et al., Formation of Dispersed and Porous Metals by Combustion of Complex Compounds of Nickel and Copper, J.Mater. Synth. Process., 1997, vol. 5, no. 5, pp. 371–377.
Boldyrev, V.V., Tukhtaev, R.K., Gavrilov, A.I., et al., Combustion of Coordination Compounds of Nickel and Copper Nitrates with Hydrazine Derivatives as a Method for Preparation of Fine-Particle and Porous Metals, Zh.Neorg. Khim., 1998, vol. 43, no. 3, pp. 362–366.
Tukhtaev, R.K., Gavrilov, A.I., Savel'eva, Z.A., et al., Effect of Pressure on Cadmium Sulfide Synthesis by Combustion of the Cadmium Nitrate–Thiosemicarbazide Complex, Dokl. Akad. Nauk, 1997, vol. 355, no. 5, pp. 646–647.
Tukhtaev, R.K., Gavrilov, A.I., Saveljeva, Z.A., et al., The Effect of Nitrogen Pressure on the Synthesis of CdS from [Cd(NH2C(S)NHNH2)2](NO3)2 Using Combustion Method, J. Mater. Synth. Process., 1999, vol. 7, no. 1, pp. 21–24.
Campbell, M.J. and Grzeskowiak, R., Some Copper(II) Complexes of Thiosemicarbazide, J. Chem. Soc., 1967, no. 3, pp. 396–401.
Samus', N.M. and Ablov, A.V., Cobalt(III) Complexes of Thiosemicarbazide, Zh. Neorg. Khim., 1961, vol. 6, no. 9, pp. 2038–2042.
Mahadevappa, D.S. and Murthy, A.S. Ananda, Some Complexes of Zinc(II), Cadmium(II) and Mercury(II) with Thiosemicarbazide, Aust. J. Chem., 1972, vol. 25, no. 5, pp. 1565–1568.
Ablov, A.V., Gerbeleu, I.V., Gol'danskii, V.I., et al., NMR Study of Iron(II) Complexes of Thiosemicarbazide, Zh. Neorg. Khim., 1971, vol. 16, no. 1, pp. 184–188.
Rosenheim, A. and Meyer, V., Uber thiokarbamidverbindungen zweiwertager Metallsalze, Z. Anorg. Chem., 1906, vol. 49, no. 1, pp. 13–27.
Khimicheskaya entsiklopediya (Encyclopedia of Chemistry), Knunyants, I.L., Ed., 5 vols., Moscow: Sovetskaya Entsyklopediya, 1988–1995.
Vanyukov, A.V., Isakova, R.A., and Bystrov, V.P., Termicheskaya dissotsiatsiya sul'fidov metallov (Thermal Dissociation of Metal Sulfides), Alma-Ata: Nauka, 1978.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Tukhtaev, R.K., Boldyrev, V.V., Gavrilov, A.I. et al. Metal Sulfide Synthesis by Self-Propagating Combustion of Sulfur-Containing Complexes. Inorganic Materials 38, 985–991 (2002). https://doi.org/10.1023/A:1020508817410
Issue Date:
DOI: https://doi.org/10.1023/A:1020508817410